Off the shoulder beautifully and simply accessorised: chain necklaces (I love seeing a bare neck/back with a pendant at the back rather than the front) + centre parted chignon/bun. I think this would look gorgeous with statement earrings (instead of a necklace) as well....
Recreate Vanessa's look (kind of):
White off the shoulder blouse - Nicholas N Broderie off the shoulder blouse, Marques' Almeida off the shoulder cotton poplin top, Tibi off the shoulder blouse, Milly off the shoulder poplin blouse, Topshop off shoulder bardot blouse, Isolda Fru Fru off-shoulder blouse, Love Off shoulder tunic, Rebecca Minkoff Celestine eyelet top, Chloe Eyelet off the shoulder blouse, Vince off the shoulder blouse, Susana Monaco Off the shoulder blouse, Rebecca Taylor off-the-shoulder poplin top, or Givenchy off the shoulder top in satin and chiffon (hello off the shoulder evening number!).
White distressed jeans - J Brand Georgia distressed slim boyfriend jeans, AG The Ex Boyfriend Jeans, Current/Elliott Boyfriend Jeans with distressing, Lovers + Friends Ezra jeans, One Teaspoon Awesome Baggies Distressed jeans, Res Denim Romeo Boyfriend jeans, New Look ripped and distressed boyfriend jeans, or 7 For All Mankind Josefina destroyed cropped jeans
